exchemist
Valued Senior Member
I only knew Ehrenfest from his paradox. Interesting.I'm getting into pretty esoteric details with a lot of math involved, and it's especially surprising how much of the modern narrative is partially or completely wrong. For instance Niels Bohr derived his atomic model based on a combination of the correspondence principle (quantum mechanics needing to reduce to classical mechanics at large scales) and fitting to Rydberg's hydrogen spectrum formula which was already known from experiments, finding that quantization of angular momenta was the key. However at the same time Bohr was publishing his paper, a man named Paul Ehrenfest was deriving this same model by showing that quantization of angular momentum (and other adiabatic invariants) is an absolute necessity in order for Planck's radiation law to be consistent with statistical mechanics, not just an easy option. In the case of the photoelectric effect, it actually only formed a tiny portion of Einstein's photon argument and was used mainly as an example of it working in practice, because most of his argument was actually based on pure thermodynamics.