"Blue" describes the experience of the color, rather than the external cause of that experience. So, the sky is blue not just because of the compositon of it... that alone wouldn't give us a sensation of a blue sky. To get blue involved, we have to involve the way our eyes interact with photons and the methods through which the optic nerve sends the "data" to the brain and causes a pattern of neuron firings which result in the experience we call blue. This experience is logically and causally related to what's in the sky, but it's not at all the same composition as what's actually in the sky since what we experience isn't sky but is actually a pattern within the mind/brain.