I've alluded to it before, but there is a process by which complex hydrocarbons, and substituted hydrocarbons can be broken down into simpler Alkanes. It has the advantage of being able to accept any kind of feed-stock, not just biomass, IIRC the highest yields come from running plastics through the process (the ultimate in recycling - recycling plastics back into light crude), although the feedstock does affect the ratios of the various molecular weights of the alkanes you get out of it - IE some will produce more Methane and less C8 Alkanes than others).
It's essentially an accelerated (non biological) adaptation of the process nature uses.
There have been test facilities, including one in the US that accepted waste from a butterball turkey plant, that have met with varying degrees of success, however it hasn't been implemented widely because the application of the technology and processes is still rather newish, and while some variations consume less energy than is contained in a barrel of the crude they produce, others do not.