... The e-folding time for sulfur-dioxide -> Sulfuric acid in the stratosphere is on the order of one month. Here (I hope)
is a paper discussing the life cycle of stratospheric aerosols.
thanks for the link. I'm not surprised by a month to form tiny weak H2SO4 drops in the stratosphere. Not much SO2 up there and if I understood on quick skim it was convected up there from lower layers. What did surprise me was how un-important gravity is in even the stratosphere:
"we can get an idea of the residence time of the aerosol particles by assuming the size distribution of Fig. 7 and evaluating the fall velocity for conditions equivalent to 22-km altitude and 220-K temperature. We obtain fall speeds of the order of 1.0 ´ 10-3 cm s-1 for particles of radius 0.06 mm and of the order of 5.0 ´ 10-3 cm s-1 for particles of radius 0.25 mm. At these rates, it would require 6.3 yr and 1.3 yr, respectively, for these particles to fall 2 km to an altitude of 20 km. Thus the sedimentation of aerosol particles is not an effective removal mechanism, except for the very few particles that somehow survive long enough in the stratosphere to grow to large sizes (i.e., an appreciable fraction of a micron in radius)."
I knew that gravity did little in the lower layers to change the molecular mix of the air (but of course makes warm air masses rise) but believed it was why H2 molecules were more lost to space than O2. Its effect must be still higher.
Both the following, I think, may be in part at least what I have been calling the "Hadley cell" transport. - is that correct?
"we assume that air rises in the Tropics, moves out of the Tropics, and descends into the extratropical lower stratosphere (the lowermost stratosphere). This is, of course, essentially
the Brewer–Dobson circulation described by Brewer (1949) and Dobson (1956). Once the air has descended into this region of the stratosphere, it can be transported isentropically into the troposphere. Aerosol particles are, of course, carried along with these air masses. As soon as the particles reach the troposphere they are lost, primarily by scavenging in clouds."
AND
"The aerosol is eventually transported to midlatitudes, crossing the boundaries of the “leaky tropical pipe” (Plumb 1996) in the 15°–30° latitude range. " and in Figure 1, the north going arrow called the
"Tropical Pipe." If yes - why has Hadley lost the credit?
They make frequent reference to "isoentropic" I assume that is saying that turbulent dissipation is not important. - Is that correct?
It is a good paper, but I doubt I will study it much. Point me to any section you think contradicts or lessens my concern that large tropical fire may make big global warming impact, both by the large CO2 "burp" * and by very significant lowering of the albedo of high clouds and warmed soot in them evaporating water drops it collided with - a "double whammie" as increased local H2O vapor from the drop is strong IR escape blocker while the clean water drop (at least reduced in size if not all gone) helped keep the cloud's albedo high.
* I forget but seem to recall that burning all the Amazon would make a few years worth of man's release of CO2 but I still fear a tiny fraction of very small black soot added to the now clean very high cloud (even the ice crystals) is an even greater GW stress. - might send significant part of the tropics into local thermal run-a-way, as section of SW Pacific Oceans already is. That could become self-sustaining even if the soot slowly was taken back down as the evaporation increase may feed on its self - as seems to be the cause for the enduring Pacific Hot Spot's local thermal run-a-away NASA's Ames center is studying.
I'm sure you know but for others: "local thermal run-a-away" just means that in some local region, more solar heating than IR energy removal is happening. The excess is mainly convected away to keep it (we hope) from becoming an expanding run-a-way region.