Quarkhead:
Second $$E=pc$$ is exactly equivalent - note that classically $$p=mv$$ (where $$v$$ is velocity) and and that the velocity of the photon is $$c$$ any one can see that this implies $$E=(mc)c$$, but this is not the point.
I don't see how it you get from $p=mv$ to $E=mc^2$, according to how you describe it. It looks like you're taking a Newtonian formula for momentum and sort of waving your hands vaguely until you produce the relativistic rest energy formula. I'd say the actual derivation is not so obvious.
I mean, for starters, if you wanted to start with Newtonian kinetic energy and then naively replace the velocity with the speed of light, then you'd end up with $E=\frac{1}{2}mc^2$ rather than $E=mc^2$. And besides, there's the whole problem with $m=0$ for photons.
As a matter of interest (or not) in the wave interpretation of Quantum Mechanics, the substitution $$p \to i\hbar \frac {\partial}{\partial x}$$. Make of that whatever you can!
The state of a quantum system is given by a state vector, $$\psi$$ (say). Any potentially measurable property of this system is described as an operator $$O$$ acting on the state vector. Momentum is one such, as you say - in itself it requires no operand to be potentially measurable.
You're agreeing with exchemist, there, apart from the bit about needing no operand. You said yourself that the operator $O$ operates on a state vector $\psi$. That state vector is the operand that is required. The result of $O$ operating on $\psi$ is that you get a number multiplied by $\psi$, provided that $\psi$ is an eigenvector of the operator, of course.
In the case of momentum, the substitution you mentioned above is the momentum
operator. Without a state vector to operate on, that does nothing.
The actual measurements - actual momenta - are given as the eigenvalues of the operator acting on the state vector.
Correct.
No, that is not at all what I said. Momentum is a property of the system and is given by the momentum operator (in QM).
The momentum of a system is the outcome of a measurement made on that system. Until you measure it, the system may not have a definite momentum.
The eigenvalues are the possible numerical values that this property is allowed to take.
Correct.