http://cdiac.ornl.gov/trends/atm_meth/ice_core_methane.html said:
This page introduces ice-core records of methane (CH4) extending back 800,000 years at Dome C, Antarctica and over 400,000 years at the Vostok site. Links are also provided to shorter records from other Antarctic locations. The 2000-year record from Law Dome, Antarctica, has been merged with modern records to create a long-term record to the present.
These records are maintained by the World Data Center for Paleoclimatology, National Oceanic and Atmospheric Administration (NOAA), and have graciously been made freely available for access and distribution. The original investigators made the effort to obtain the data and assure their quality.