I know that there will be 2 solutions, 1 for before collision, and the other is at minimum separation. But I don't know which is which...neither 6m/s nor -2m/s matches the given information that at minimum separation, both are moving at +2m/s
Careful. Is the total kinetic energy equal to 70.0625 J at the point of minimum separation? The two solutions are for when none of the energy is potential energy.
Oh! So the correct answer is -2m/s for the 3 kg cart and 8m/s for the 2kg cart. And the 2m/s coming out as a solution has nothing to do with the 2m/s[E] at minimum separation... 6m/s and -4m/s actually represents the velocities of the two carts AFTER the collision. What if the question didn't tell you anything about the initial directions of the carts? Will there be 2 different sets of answers that are both valid?
You'd get the same two answers, but you wouldn't be able to tell which were the initial and which were the final velocities, based on the information given.