Again, I made a assumption of understanding, and didn't explain my thoughts fully, I should have said that we are at the most concentric orbit of the eccentricity of the Malinkovitch Orbital Cycle, which accounts for the low variation in the Insolation.
I understand what you mean, but i'm not sure that it's correct to refer use concentric in this context (it could be) least eccentric or most circular are the phrases i've usually seen used to describe it.
Yes, the orbit of the earth has the Aphelion, and a Perihelion, not the Milankovitch Cycle, bow that clears up some of my confusion of statement.
Glad to be of service.
But my question is that CO2 lags behind the warming cycle, and as the levels of CO2 peak, cooling appears to occur, so from what I am reading and see, could it be Possible for CO2 to be a Ice House Gas, not a Green House Gas?
The short answer is no, I'll try and explain more later.
The Ice Core samples show a lag in CO
2 and CO
2 increase to a maximum, not sure where that point is, the turnover takes place and cooling occurs, and the CO
2 again lags the cooling until we reach the bottom of the cycle and CO
2 and CH
4 are again locked in the carbon sinks, of bottom ocean ice and tundra.
http://www-odp.tamu.edu/publications/199_SR/synth/synth_7.htm
I am getting a picture in my head, that with out CO
2 that warming cycles would be much more sever, that CO
2 just might be a damper on warming, and that once it attains a catch up point to the warming, it causes the change over to the next cooling cycle, along with the other cycles, and is the forcing of the cooling?
??????????
Prehistoric global cooling caused by CO2, research finds
Feb 26, 2009 ... "Previous reconstructions gave no evidence of high-latitude cooling," ... How Earth's temperature changed during this climate transition ...
news.uns.purdue.edu/x/2009a/090226HuberPete.html - 13k - Similar pages
Essentially, greenhouse gasses are so called because they have the property that they absorb strongly in the infra-red part of the spectrum. This absorbed radiation is converted into thermal energy, and eventually released again as infra red radiation of (I think) the same wavelength. This means that, roughly speaking about half of the radiation that the carbon dioxide absorbs, that would ordinarily have been radiated back into space, is emitted downards, back to the ground. Some of this will be absorbed by other carbon dioxide molecules, heating the atmosphere, and some of it will be absorbed by the ground, heating the ground.
This
website has some good information on the physics behind what happens, and shows a spectrum of sunlight passed through carbon dioxide.
The graph below:
Is courtosey of the
TPF Book
It shows the thermal spectrum of earth as seen from space. The red line is the ideal blackbody curve, the purple one is the measured spectrum.
Here is the same for Carbon Dioxide:
And Water:
Linked is Methane:
http://tpf.jpl.nasa.gov/library/tpf_book/gallery/images/4-6-ch4.jpg
The importance of a gas as a greenhouse gas is based on the location of the absorption feature in the spectrum, and the strength of the absorption feature.
The thing about gasses as they obey this thing called
Henry's Law.
One of the consequences of this is that as the partial pressure of the gas in the atmosphere - essentially it's concentration increases, so does the solubility of that gas in water, but, as the temperature decreases the solubility of the gas increases.
This article talks about the Carbonate Compensation Depth. Essentially, what that means, is if you drop a sea shell into the Marianas trench, it will fall, above a certain depth, the calcium carbonate is insoluble, but, the solubility of the calcium carbonate varies in a predictable way with depth, pressure, and the concentration of CO2 in the water (which in turn depends on the Temperature, and the partial pressure of atmospheric CO2).
The reason that it depends on the CO2 is that when calcium carbonate dissolves in water the following occurs:
$$CaCO_3 \rightleftharpoons Ca^{2+} + CO_3^{2-}$$
The Carbonate then reacts with water thusly:
$$CO_3^{-2} + H_3O^+ \rightleftharpoons HCO_3^- + H_2O$$
However, when we dissolve Carbondioxide in water, this also sets up an equilibrium reaction in the water:
$$CO_2 + 2H_2O \rightleftharpoons HCO_3^- + H_3O^+$$
These to sets of equations work in synergy to give:
$$CaCO_3 + CO_2 + H_2O \rightleftharpoons Ca^{2+} + 2HCO_3^-$$
Anyway, the CCD represents the depth in the ocean at which the rate at which calcium carbonate is dropped from above is equal to the rate at which it dissolves, below this depth, no calcium carbonate is preserved as deposits on the sea floor.
Now, if I've remembered everything correctly (this is third year environmental chemistry we're talking about at the moment).
Increasing the amount of carbon dioxide in the atmosphere increases the amount of carbon dioxide in the oceans, which raises the level of the CCD (assuming the temperature remains constant).
Lowering the temperature of the oceans increases the solubility of calcium carbonate in the water which raises the level of the CCD (assuming the concentration of carbondioxide in the water stays constant).
However, lowering the temperature of the ocean
also increases the solubility of carbondioxide in the water, which increases the concentration of carbondioxide in the water, which adds to the lowering of the CCD.
So, in a situation where you have rising temperatures, and constant pp CO2 in the atmosphere, the CCD would lower (it would become deeper).
In a situation where you have a rising pp CO2 in the atmosphere, but a constant temperature, the CCD would also lower.
But, in a situation where you have, for example, a rising pp CO2 and a rising temperature, whether the CCD rises or lowers depends on which effect is more important, and it may well be that there is some threshold level (as there often is with opposing trends) where first you see the CCD lowering, and then rising (or vice versa).
I hope that's helpful, I think I have a couple of more things I want to say, but just at the moment I lack time.
As I said, this is third year environmental chemistry we're talking about at the moment.