Anomalous properties of lithium

Discussion in 'Chemistry' started by Lamont Cranston, Nov 17, 2009.

  1. Lamont Cranston Registered Senior Member

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    I spotted recently that the commonest isotope of Li is Li-7 (atomic no=3, mass number = 7). This means that the nucleus contains 4 neutrons.

    According to conventional wisdom the 4th neutron is not necessary, because the nuclear stability only requires 3 neutrons.

    This pattern certainly holds true of all other light elements where the no. of protons = the no. of neutrons in their most abundant isotope.

    Can anyone explain the anomalous nature of lithium?
     
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  3. Trippy ALEA IACTA EST Staff Member

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    Lithium is not anomalous in behaviour.

    Li-7 being more common than Li-6 is explanable by Big-Bang Nucleosynthesis (there are two pathways I know of for Generating Li-7).

    Lithium 6 on the other hand is very difficult to make in the big-bang, it requires the fusion of He-4 and Deuterium which has a very small cross section (it's not very likely to happen except in a very small proportion of collisions as detailed inPrimordial synthesis of Li-6 and the rate of alpha-/d, gamma/ Li-6.

    Lithium 6 is as stable as Lithium 7, it's just that as it turns out it takes very little energy to turn Lithium 6 into Tritium.

    So why is there more Lithium 7 than Lithium 6 in the universe? It's not because Lithium 7 is stable and Lithium 6 isn't, it's just because Lithium 7 is easier to make in a big bang than lithium 6 is.
     
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  5. Captain Kremmen All aboard, me Hearties! Valued Senior Member

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    A fine answer.
    :worship:
     
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  7. Lamont Cranston Registered Senior Member

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    Many thanks Trippy. Sounds feasible...
     
  8. Captain Kremmen All aboard, me Hearties! Valued Senior Member

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    Yes, if it isn't the right answer, it ought to be.
     
  9. Trippy ALEA IACTA EST Staff Member

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    :shy:
    Thanks.
     

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