C-C bond energy is 347 kJ/mol & C-O bond energy is 358 kJ/mol. Question: So, can carbon and oxygen make chemical bond as diamond but can be stiffer than diamond ?
Not really. One C-O single (sigma) bond is slightly stronger than one C-C bond. But "stiffness" is a term that applies to a whole substance rather than a single bond. Diamond is a 3D "giant structure", involving a network of C-C bonds all connected together. There are no discrete molecules in this type of structure: the whole crystal is effectively one giant molecule - hence the term "giant structure". There is no such structure possible using C-O bonds. The only stable compounds of carbon and oxygen are small molecules (CO and OCO). These do not have any "spare" bonding available to link one molecule to the next. Consequently both of these (carbon monoxide and carbon dioxide) are gases at RTP. If you were to try to synthesise something with a network of C-O-C linkages, it would decompose.
Ajanta, having thought some more about your question, I have realised my first answer is rather unsatisfactory. You might well ask why it is that a giant structure of C-O bonds is not a stable arrangement. In fact, if you consider silicon, the element that lies immediately below carbon, in the same group of the Periodic Table, and which has therefore a number of chemical similarities with carbon, a stable giant structure is exactly what is formed by its compound with oxygen. This is SiO2 or quartz - a brittle, very hard mineral, which looks, er, a bit like diamond! The real reason why carbon oxides do not form such 3D extended structures is the strength of the C=O double bond. The strength of the C=O bond is far greater than that of the analogous Si=O bond. So, for carbon, a structure with C=O double bonds is more stable than one involving only C-O bonds, whereas for Si the opposite is true. The next question is why there is this difference between Si and C in their propensity to form double bonds with oxygen. You may or may not know that a double bond involves 2 bonds of different sorts: a "sigma" bond which extends more or less along the line of the two centres of the atoms at either end, and a pi bond which is made of two parts, one above and one below the line of the centres. The pi bond arises from an overlap of p orbitals on the atoms at either end. These p-orbitals extend like dumbbells, or figures of "8", at right angles to the line of the atomic centres, like this: 8-8. The p-orbitals of carbon and oxygen are both 2p, that is, they are from the 2nd shell of electrons around the atom. They are thus of similar size and shape and overlap between them is quite efficient, leading to a strong pi bond. Si however, being in the next period of the table, has 3p orbitals, not 2p. These are larger and more diffuse than 2p and will not overlap efficiently with the 2p orbitals on oxygen, leading to only a weak pi bond. So there you have it. It is the strength of the double bonding between carbon and oxygen that gives it more energetically favourable options than the formation of a giant structure. I should probably add that there will also be an entropy term to consider. Formation of a lot of little molecules, each with numerous degrees of freedom, is a higher entropy state than a solid giant structure. So this too will help to tilt the playing field in favour of the gaseous molecular compounds, provided they are energetically stable enough. Right. That is now a proper answer, I think. Please Register or Log in to view the hidden image!
Thank you sir ! Yesterday I thought to make a question to you about SiO2 only but you made it and solved it and others.
Good! In fact there is a thing called the "double bond rule", which like a lot of "rules" in physical science is not always obeyed, but nevertheless has a measure of validity: https://en.wikipedia.org/wiki/Double_bond_rule There are P=O and S=O double bonds in the standard structures for phosphate and sulphates, but these appear to be quite weak, as shown by comparing the bond lengths of the double and single bonded oxygen in these compounds.
